Imagine you have a bunch of tiny little balls (atoms or molecules) that are flying around in a big space. Now, let's say that some of these little balls bump into each other and then stick together. But, sometimes they don't stick together because they're moving too fast or they don't bump into each other just right.
Now, let's say you have a bigger ball (a molecule) that is trying to stick to one of these little balls, but it keeps missing. This can be frustrating for the bigger ball because it really wants to stick to the little one.
But here's where the cage effect comes in. Sometimes the little balls that are flying around actually form a little cage around the bigger ball, keeping it in place for just long enough that it can stick to the little ball it wants to stick to. It's like the little balls are working together to help the bigger ball out.
So, in summary, the cage effect is when a bunch of little balls form a temporary cage around a bigger ball (like a molecule) to help it stick to another little ball that it really wants to stick to. It's kind of like teamwork!