So, you know how sometimes when you put your hand up to the TV or radio, you can feel the heat coming off of it? Well, that heat is actually made up of something called radiation. That may sound scary, but radiation is actually all around us all the time, and we can't see or feel it most of the time.
Now, when we talk about radio waves, we're talking about a specific type of radiation that's used to transmit things like music, news, and TV shows over the airwaves. And just like how different types of light have different wavelengths (which is why we can see different colors), different types of radio waves have different frequencies.
That's where the radio window comes in. Basically, there are certain frequencies of radio waves that can pass through the Earth's atmosphere without being blocked or absorbed. This "window" allows us to send and receive radio signals from space, and it's also why most of our communication technology (like Wi-Fi and cell phones) use frequencies that fall within the radio window.
So think of it this way: imagine the Earth is an umbrella made of different materials that can let through some types of raindrops but not others. The radio window is like the part of the umbrella that's made of a special material that lets through certain types of raindrops that wouldn't be able to get through if the umbrella were made of a different material. And just like how we can use that special part of the umbrella to stay dry, we can use the radio window to communicate with people all over the world (and even in space!) using radio waves.