ELI5: Explain Like I'm 5

Chemical shift

Chemical shift is a way that scientists use to figure out what kinds of atoms are in a molecule. Think of it like a secret code that reveals information about the atoms in a molecule!

Imagine if you and your friend were sending each other secret messages. You might decide that when you say the word "apple," it really means "banana." So if your friend writes you a message with the word "apple" in it, you'll know to think about bananas instead!

Chemical shift works kind of like that. When scientists put a molecule into a special machine called a nuclear magnetic resonance spectrometer (NMR for short), it measures how the atoms in the molecule respond to a magnetic field. This creates a signal that looks like a little graph with peaks and valleys.

Each peak on the graph is like a secret code, telling the scientists something about the atoms in the molecule. Specifically, it tells them about the "shielding" of the atoms, which is a fancy way of saying how the electrons around the atom are arranged.

Different types of atoms have different "shielding" patterns, which means they produce different peaks on the graph. So by looking at the chemical shift graph for a molecule, scientists can figure out what kinds of atoms are in it!

Just like how "apple" might mean "banana" in your secret messages, different peaks on the chemical shift graph mean different kinds of atoms in the molecule. For example, if there's a peak at a certain spot on the graph, that might mean there's a hydrogen atom attached to a carbon atom in the molecule.

So chemical shift is basically the secret code that scientists use to decode the atoms in a molecule!