Okay, imagine you have a magic word that will only work if you say it with a certain special item, like a wand or a special necklace. This magic word won't work if you don't have the special item. That's kind of like a negative polarity item in grammar!
A negative polarity item is a word that can only be used in certain situations, usually when there is a negative word nearby like "not" or "never". For example, the word "barely" is a negative polarity item because you usually only use it when something hasn't happened or almost didn't happen, like "I barely made it to the store before they closed" or "He barely passed his test".
Negative polarity items are like the special item in the magic word example - they only work in certain situations. Just like you can't say the magic word without the special item, you usually can't use a negative polarity item without a negative word nearby. It's a special rule in English grammar!