ELI5: Explain Like I'm 5

Bent's rule

Bent's rule is kinda like how you can change the shape of a toy by putting different pieces together.

Imagine you have a toy car that you can take apart and put back together. Now, let's say you have two different kinds of wheels - big ones and small ones. If you put all big wheels on the car, it'll be really tall and won't work well. If you put all small wheels on, it'll be really short and won't work well either.

But if you mix them up - put two big wheels in the back and two small ones in the front - it'll work much better!

Bent's rule is kinda like that, but with atoms.

When atoms come together to make molecules, they can twist and bend to make the best use of their electrons. Electrons are little particles that zoom around atoms and hold them together in molecules.

Bent's rule says that some atoms will change their shape a bit to make use of their electrons in the best possible way. Just like how the toy car worked best with a mix of big and small wheels, molecules work best when the atoms are arranged just right.

So, instead of putting all the big wheels (or all the small ones) in one place like in the toy car, the atoms kinda "mix and match" to be in the best position to hold onto their electrons. This helps the molecule be strong and stable.

Overall, Bent's rule helps us understand how and why molecules have the shapes they do, based on the way the atoms join together and share electrons. It's kind of like a puzzle where all the pieces have to fit just right!